Application Notes

Multiple reflection ATR is ideal for detecting miniscule levels of components in solutions. If one component is volatile, trace analysis can be simplified by allowing the volatile liquids to evaporate.

The miniDOAS: Low Cost, High Performance Contactless Ammonia Measurements

Transportable Dual-Band Raman System for Fuel Analysis

Probing the Detection Limits of Concentrated Multiple Reflection ATR Spectroscopy

Improved Sensitivity with the New Apollow XRF ML-50 Detector on the Orbis Micro-XRF Analyzer

Determination of Low Concentration Methanol in Alcohol by an Affordable High Sensitivity Raman Instrument

Bruker Daltonics, Inc.

Proton OnSite

Experimental data show the crystal dimensions of an ATR-FT-IR sampling accessory influence the usable spectral range. An expanded range germanium crystal is introduced for the measurement of high refractive index samples.

Single reaction chamber (SRC) microwave digestion offers multiple benefits over traditional dry ashing for the sample preparation of heavy crude oils for trace metals analysis. These include increased sample throughput, reduced risk of contamination, more complete digestion and retention of volatile analytes.

Quantifying protein stability is of fundamental importance in many areas of biomolecular research. The thermodynamic stability of a protein is reflected by a change in Gibbs free energy, ?G?, characterizing the equilibrium transition from a folded state, to an ensemble of unfolded, denatured states. In order to study ?G?, the folding equilibrium needs to be shifted towards the unfolded states which can be achieved by several different methods including the addition of chemical denaturants such as guanidinium chloride (GdnHCl).

Biological tissues and other materials often autofluoresce at near-infrared wavelengths, prohibiting Raman acquisition. New, dispersive Raman systems at 1064 nm allow fluorescence-free measurement in similar integration times.

Moxtek's ULTRA-LITE X-ray source is a very small self contained X-ray source (X-ray tube and high voltage power supply) for use in portable X-ray applications, such as the handheld X-ray florescence (XRF) spectrometers. This note demonstrates that this X-ray source has a stable and repeatable X-ray flux output over time, which is vital for the precision of the calibrated XRF measurements.

Building on more than 10 years of Micro-XRF experience, the Orbis spectrometer yields a system with excellent Micro-XRF capability while setting a new standard in analytical flexibility. The Orbis incorporates a unique motorized turret integrating video and X-ray optics allowing coaxial sample view and X-ray analysis. The turret can accommodate two additional collimators along with the X-ray optic for a total of three X-ray beam sizes to expand the Orbis analytical capabilities beyond traditional Micro-XRF analysis.

Elemental analysis of aqueous solutions into the low ppm and sub-ppm concentration ranges is demonstrated, using the advanced Cartesian geometry Rigaku NEX CG Energy Dispersive X-ray Fluorescence (EDXRF) spectrometer in conjunction with the patented UltraCarry? sample preparation technique.

Identifying contaminants in materials is a common troubleshooting need for which FT-IR spectroscopy is ideally suited. Thermo Scientific OMNIC Specta software provides a unique and powerful tool to assist the analyst to quickly identify unexpected constituents. The OMNIC? Specta? Contaminant Search feature allows for rapid investigations that can save time and minimize the impact of product issues.

The US EPA wrote wastewater effluent limit guidelines for discharge permits granted to coal-fired power plants back in 1982, known as 40 CFR Part 423. However, the rule has not kept pace with changes in the industry over the past several decades. For that reason, the US EPA has revised the rule with new proposed revisions expected in November 2012 and the final rule expected by April 2014. To support the modification to this rule, the US EPA is developing a new ICP-MS method specifically for flue gas desulfurization wastewaters (FGDW).

This paper demonstrates an ICP-MS method for the determination of total and As species concentrations in organic brown rice samples (OBRS).

Clays, like kaolinite and smectite, are hygroscopic and it is well known that the adsorbed water can be driven off at elevated temperatures. At very low temperatures, in addition to the typical band narrowing and shifting, changes in the O-H bond vibrational modes of clays have also been observed.

Near-infrared spectroscopy (NIR) is a powerful technique for rapid and non-destructive material analysis. Scientific breakthroughs over the past several decades have made NIR one of the most powerful tools for research, especially in industries such as food and drug, chemical, oil and gas, and plastics. This technique has mainly been limited to non-portable applications due to instrument size, fragility, and cost. Additionally, Database Search Software or Multivariate Prediction Software must also be employed to extract results; however, user-friendly and cost effective solutions have not been widely available.

Modern paints and varnishes are complex mixtures and the organization of the material properties is an important task. One of the most essential variables is the curing which should in most cases take place in a reasonably short time span that can range from a fraction of a second to many days. It is difficult to evaluate the degree of curing and its completeness by visual inspection.

Low concentration natural methanol exists in most alcoholic beverages and usually causes no immediate health threat. Nevertheless, it is possible to have natural occurring methanol in beverages with concentration as high as 18 g/L of ethanol; or equivalent to 0.72% methanol in 40% ethanol, in alcohol (1). Current EU regulation limits naturally occurring methanol to below 10 g/L of ethanol; or equivalent to 0.4% methanol in 40% ethanol.

Knowledge about the morphology and chemical composition of heterogeneous materials on a submicrometer scale is crucial for the development of new material properties for highly specified drug delivery systems. WITec's ultrasensitive and modular alpha300 and alpha500 microscope series allow for the analysis of the chemical characteristics of a sample three-dimensionally, underneath and at the surface. Confocal Raman microscopy for 3D chemical imaging and TrueSurface Microscopy employed for topographic Raman imaging deliver the highest spectral quality and unmatched spatial resolution.

The measurement of P, S, Ca, and Zn in lube oil is demonstrated as per ASTM D6481-99(2010).

Building on more than 10 years of Micro-XRF experience, the Orbis spectrometer yields a system with excellent Micro-XRF capability while setting a new standard in analytical flexibility. The Orbis incorporates a unique motorized turret integrating video and X-ray optics allowing coaxial sample view and X-ray analysis. The turret can accommodate two additional collimators along with the X-ray optic for a total of three X-ray beam sizes to expand the Orbis analytical capabilities beyond traditional Micro-XRF analysis. Primary beam filters can be used with all spot sizes available on the turret to allow true XRF analytical capabilities in a micro-spot analysis. The working distance is increased to allow analysis over rougher sample topography without sacrificing signal intensity.

Increased capability for identifying genuine versus counterfeit materials is achieved by using dispersive 1064 nm Raman analyzers.

Cement is one of the most important materials in the construction industry. Traditionally, WDXRF spectrometers used in cement plants have been large, floor-standing models with substantial installation requirements and ownership expenses. This application note demonstrates the capabilities of the Rigaku Supermini - a new low-cost, benchtop wavelength dispersive X-ray fluorescence (WDXRF) spectrometer - for the rapid quantitative elemental analysis of cement raw meal.

Infrared (IR) sampling techniques of attenuated total reflectance (ATR) and transmission for polymer analysis are compared and contrasted. Using a real-world application, IR analysis of silane-grafted linear low density polyethylene (LLDPE) pellets is presented to illustrate the benefit of IR film transmission sampling.

The polyclonal IgG in this study is more thermally stable at neutral pH, (4.8 to 7.8) than it is at lower pH. The loss of thermal stability at lower pH is concomitant with a change in the pre-transition folded structure of the protein.

Raman is a well-developed and implemented qualitative spectroscopic tool for molecular identification, but in recent years with the development of high resolution portable Raman spectrometers and cutting edge chemometric modeling, software has now enabled the use of Raman for highly precise quantitative measurements of mixtures and reactions.