Application Notes: General

Building on more than 10 years of Micro-XRF experience, the Orbis spectrometer yields a system with excellent Micro-XRF capability while setting a new standard in analytical flexibility. The Orbis incorporates a unique motorized turret integrating video and X-ray optics allowing coaxial sample view and X-ray analysis. The turret can accommodate two additional collimators along with the X-ray optic for a total of three X-ray beam sizes to expand the Orbis analytical capabilities beyond traditional Micro-XRF analysis.

Identifying contaminants in materials is a common troubleshooting need for which FT-IR spectroscopy is ideally suited. Thermo Scientific OMNIC Specta software provides a unique and powerful tool to assist the analyst to quickly identify unexpected constituents. The OMNIC? Specta? Contaminant Search feature allows for rapid investigations that can save time and minimize the impact of product issues.

Clays, like kaolinite and smectite, are hygroscopic and it is well known that the adsorbed water can be driven off at elevated temperatures. At very low temperatures, in addition to the typical band narrowing and shifting, changes in the O-H bond vibrational modes of clays have also been observed.

Near-infrared spectroscopy (NIR) is a powerful technique for rapid and non-destructive material analysis. Scientific breakthroughs over the past several decades have made NIR one of the most powerful tools for research, especially in industries such as food and drug, chemical, oil and gas, and plastics. This technique has mainly been limited to non-portable applications due to instrument size, fragility, and cost. Additionally, Database Search Software or Multivariate Prediction Software must also be employed to extract results; however, user-friendly and cost effective solutions have not been widely available.

Low concentration natural methanol exists in most alcoholic beverages and usually causes no immediate health threat. Nevertheless, it is possible to have natural occurring methanol in beverages with concentration as high as 18 g/L of ethanol; or equivalent to 0.72% methanol in 40% ethanol, in alcohol (1). Current EU regulation limits naturally occurring methanol to below 10 g/L of ethanol; or equivalent to 0.4% methanol in 40% ethanol.

Building on more than 10 years of Micro-XRF experience, the Orbis spectrometer yields a system with excellent Micro-XRF capability while setting a new standard in analytical flexibility. The Orbis incorporates a unique motorized turret integrating video and X-ray optics allowing coaxial sample view and X-ray analysis. The turret can accommodate two additional collimators along with the X-ray optic for a total of three X-ray beam sizes to expand the Orbis analytical capabilities beyond traditional Micro-XRF analysis. Primary beam filters can be used with all spot sizes available on the turret to allow true XRF analytical capabilities in a micro-spot analysis. The working distance is increased to allow analysis over rougher sample topography without sacrificing signal intensity.

Increased capability for identifying genuine versus counterfeit materials is achieved by using dispersive 1064 nm Raman analyzers.

Cement is one of the most important materials in the construction industry. Traditionally, WDXRF spectrometers used in cement plants have been large, floor-standing models with substantial installation requirements and ownership expenses. This application note demonstrates the capabilities of the Rigaku Supermini - a new low-cost, benchtop wavelength dispersive X-ray fluorescence (WDXRF) spectrometer - for the rapid quantitative elemental analysis of cement raw meal.

Infrared (IR) sampling techniques of attenuated total reflectance (ATR) and transmission for polymer analysis are compared and contrasted. Using a real-world application, IR analysis of silane-grafted linear low density polyethylene (LLDPE) pellets is presented to illustrate the benefit of IR film transmission sampling.

The polyclonal IgG in this study is more thermally stable at neutral pH, (4.8 to 7.8) than it is at lower pH. The loss of thermal stability at lower pH is concomitant with a change in the pre-transition folded structure of the protein.

Raman is a well-developed and implemented qualitative spectroscopic tool for molecular identification, but in recent years with the development of high resolution portable Raman spectrometers and cutting edge chemometric modeling, software has now enabled the use of Raman for highly precise quantitative measurements of mixtures and reactions.

This technical brief compares imaging needs and how Moxtek is improving its products. It explains how competing technologies in LCoS projectors compare in terms of brightness, performance, durability and reliability.

The formation of organic silane-based thin films on silicon substrates provides a simple opportunity to introduce chemically well-defined thin films at the molecular scale (1).

FTIR spectroscopy has long been used for the analysis of art and historical objects in support of efforts to conserve, restore, and validate authenticity of these rare objects. The value of the technique for this application lies in its inherent sensitivity, specificity, and non-destructive capabilities.

Low concentration natural methanol exists in most alcoholic beverages and usually causes no immediate health threat. Nevertheless, it is possible to have natural occurring methanol in beverages with concentration as high as 18 g/L of ethanol; or equivalent to 0.72% methanol in 40% ethanol, in alcohol (1). Current EU regulation limits naturally occurring methanol to below 10 g/L of ethanol; or equivalent to 0.4% methanol in 40% ethanol.

Whether the goal is food safety, ensuring quality, or establishing provenance, measuring the trace element content of foods and beverages that we all consume is of paramount importance. While some elements are essential for our well being at low concentrations, others like lead and chromium are highly toxic and more still are being linked to viral, neurological, and other diseases. Food scares related to contamination or poor quality not only constitute a health risk, they also undermine consumer confidence. This can lead to lost earnings through reduced sales and loss of credibility through adverse publicity.

Multiple reflection ATR is ideal for detecting miniscule levels of components in solutions, both aqueous and non-aqueous. Most multiple ATR accessories use ATR crystals which are susceptible to wear and damage. Diamond, although an excellent choice due to its refractive index, high degree of chemical inertness, and low coefficient of friction, is generally not used because of its expense and its strong lattice bands around 2200 cm-1.

The Optima 8x00 ICP-OES series utilizes the new Flat Plate plasma technology that replaces the traditional helical coil design used since the inception of the inductively coupled plasma. The Flat Plate plasma technology, as seen in Figure 1, utilizes two flat induction plates to produce a plasma that is compact, dense, and robust. This plasma utilizes about half the argon required by previous helical coil designs while still delivering exceptional analytical performance.

Analysis of the temperature of the photosphere and determine the temperature by students using CCD spectrometers.

In this study, apple juice samples are analyzed by IC–ICP–MS to determine the concentration of six arsenic species: the two inorganic, and highly toxic, species (As (V) and As [III]) and four organic species (arsenobetaine [AsB], arsenocholine [AsC], monomethylarsonic acid [MMA], and dimethylarsinic acid [DMA]).

Current USP Method 231 "Heavy Metals" was introduced in 1905 for determining heavy metal impurities in pharmaceutical drug products. The procedures of the method have several limitations, which produce results that are nondiscriminatory, difficult to reproduce, and qualitative, or at best, semi-quantitative.

Pork fat was directly analyzed in this study with Bruker's FT-NIR system for iodine value (IV) with an accuracy expressed in RMSEP of 1.1 IV.

The approach to infrared measurements of diffusely scattering materials often is dictated by the objective of the analysis. Spectral data from three different mid-infrared reflectance sampling accessories are contrasted.

FT-NIR spectroscopy for the quantitative determination of key physical parameters in bulk polymers and products, including density and melt index (MI). These measurements can often be made with little or no sample preparation.

In this study, far-UV CD spectra of eight different mammalian serum albumins were measured repeatedly using automated CD spectroscopy. Two independent methods of normalizing the CD data were used to eliminate the need for accurate knowledge of protein concentration or extinction coefficient. The normalized far-UV data, representative of secondary structure, were compared to determine if there were statistically significant differences between samples. The two normalization methods agreed in every case, increasing confidence in the results.

A much discussed issue related to near infrared analysis (NIR) is the necessity of sample preparation. Ground and unground samples of wheat were analyzed to determine how truly necessary it is to homogenize samples before NIR analysis. The new Retsch TWISTER mill, specifically designed for NIR sample preparation, was utilized for this comparative study.

While crystalline silicon (c-Si) is still the material of choice for modern solar cell manufacturing, the drive toward lower cost, more efficient solar cells is prompting a renewed interest in thin-film amorphous silicon (a-Si). In light of this, it is more important than ever to have the ability to quickly identify Si crystallinity, both qualitatively and quantitatively. In this application note, we evaluate how a portable Raman spectrometer can be used in conjunction with a portable video microscope to measure crystallinity.

Recent evidence that the phthalate plasticizers may cause health problems, particularly in children, has resulted in many countries prohibiting the use of phthalates in toys and clothing. The United States Child Safety Law actually prohibits the presence of several phthalate compounds at levels exceeding 0.1 wt % even though the commercial levels are often greater than 10%. While ATR spectroscopy works well for identifying phthalates at commercial levels, a more sensitive technique is required to detect trace levels.

The Moxtek Proflux UVC266 analyzer improves UV–vis NIR spectrophotometer performance. As the analyzer polarizer, the UVC266 conserves space, offers an exceptionally wide cone acceptance angle, and has no disturbance issues as does the Glan-Taylor prism due to its air-gap.

Analyzing the effect of UV LED modules on disinfecting ballast water using UV–vis spectroscopy.